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Thermodynamics

 

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1.  Experimental determination of Phase Equilibria

 

 

172024

High pressure variable volume view cell

100_0480

Apparatus for the experimental determination of Vapor – Liquid Equilibrium. Simultaneous measurement of phase compositions and densities.

Phase compositions for the system CO2(1)-ethanol(2): (!), Experimental (T=313.2K); (·), Experimental (T=328.2K); The lines were calculated by the QCHB model.

Saturated densities for the system CO2(1)-ethanol(2): (!), Experimental (T=313.2K); (·), Experimental (T=328.2K); The lines were calculated by the QCHB model.

 

 

 

 

 

 

2.  Polymer – Supercritical fluids interactions

Gas solubility in glassy and rubbery polymers 

Sorption of CO2 in Polystyrene at 50 oC

Swelling of polymers in gas or supercritical fluid atmosphere

 

 

 

3.  Statistical Thermodynamics

 

4. Hydrogen Bonding in Fluids

 

5. Calorimetry/ Thermal Analysis

 

6. Molecular Simulation

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Thermodynamics

 

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